The Sizzling Pairs on Display at the 2023 Baby2Baby Gala: Kirsten Dunst, Jesse Plemons, and More

Hollywood's most glamorous couples came together for a charitable event at the annual Baby2Baby gala on Saturday, November 11.

Kirsten Dunst and Jesse Plemons had a night out without the kids. The couple, who tied the knot in July 2022, have two sons, Ennis (5) and James (2). Dunst, 41, looked stunning in a sleeveless, floor-length gown by Dries Van Noten, featuring an exquisite teal and lavender floral pattern. Plemons, 35, opted for a classic black tuxedo.

At the Baby2Baby event, Dunst joined several other celebrity moms in support of the organization's mission to provide diapers and essential items to underprivileged children. Among them was Jessie James Decker, who displayed her pregnancy bump in a stunning long-sleeved purple gown with a ruched side detail that accentuated her stomach. In an Instagram Story photo, she referred to herself and her husband, Eric Decker, as "mom and dad all dressed up," as he wore a dashing navy suit for the occasion.

Scroll down to see the hottest couples at the 2023 Baby2Baby gala:

Credit: Araya Doheny/Getty Images for Baby2Baby

The Hottest Couples at the 2023 Baby2Baby Gala: Kirsten Dunst and Jesse Plemons and More

Hollywood's most popular celebrity duos embarked on a charitable red carpet event on Saturday, November 11, at the yearly Baby2Baby gala.

Kirsten Dunst and Jesse Plemons relished a well-deserved evening away from parenthood. The duo, who tied the knot in July 2022, are proud parents to their sons Ennis, 5, and James, 2. Dunst, aged 41, dazzled in a sleeveless, teal and lavender floral design gown by Dries Van Noten, gracefully flowing to the floor. Plemons, aged 35, looked dashing in a classic black tuxedo.

Dunst joined other celebrity mothers at the Baby2Baby event, where they provide diapers and essential items to underprivileged children.

Pregnant with her fourth child, Jessie James Decker looked stunning in a long-sleeved purple gown. The dress featured a ruched side detail that beautifully accentuated her baby bump, and a thigh-high slit added a touch of allure. In an Instagram Story photo, she captioned the picture of herself and her husband Eric Decker, who looked dapper in a navy suit, with "Mom n dad cleaned up."

Scroll down to see the hottest couples at the 2023 Baby2Baby gala:

Credit: Lisa OConnor/AFF-USA.com/MEGA

Zoe Saldana and Marco Perego Saldana

The actress donned a white Balmain dress featuring a captivating black floral design, complemented by cap sleeves and an uneven hemline. She accessorized with elegant Reza jewelry. Meanwhile, her husband of thirteen years sported a sleek all-black attire, stylishly leaving a few buttons undone on his shirt.

Credit: Araya Doheny/Getty Images for Baby2Baby

Jordana Brewster and Mason Morfit

Bathed in radiance, the renowned actress from The Fast and Furious shone splendidly, adorned in a captivating strapless black Monique Lhuillier mini dress. Embellished with a crystal bow detail beneath a deep V-neckline, her glamorous attire was accompanied by her spouse Morfit, who exuded elegance in a sleek black tuxedo.

Credit: Araya Doheny/Getty Images for Baby2Baby

Nicole Richie and Joel Madden

The designer and musician looked very rock 'n' roll with Madden in all black and Richie in a deep red, floor-length velvet dress from Alberta Ferretti. 

Credit: Xavier Collin/Image Press Agency/MEGA

Sofia Richie and Elliot Grainge

The model wore a black sequin mini dress while her husband donned a three-piece suit. 

Credit: Lisa OConnor/AFF-USA.com/MEGA

Sarah Hyland and Wells Adams

Hyland rocked a Monique Lhuillier mini dress with purple floral details while Adams opted for a black suit with a white shirt. 

Credit: Lisa OConnor/AFF-USA.com/MEGA

Jessie James Decker and Eric Decker

The former We cover stars wore purple and blue. 

Credit: Xavier Collin/Image Press Agency/MEGA

Jenna Dewan and Steve Kazee

The engaged couple both wore black, but Dewan added a bright pop of color with the blue off-the-shoulder top of her Monique Lhuillier gown. 

Credit: Lisa OConnor/AFF-USA.com/MEGA

Zooey Deschanel and Jonathan Scott

In a sea of conventional attire, Scott stood out as one of the daring individuals who embraced a fashion gamble by donning a brown velvet suit jacket adorned with black lapels. His fiancée, on the other hand, exuded elegance in a black velvet Patou mini dress featuring a beautifully embellished waistline.

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Drew Scott and Linda Phan

The Property Brothers star and his wife both wore neutral colors with Scott donning black, gray and white and Phan wearing a strapless black dress with a white bow on the chest. 

Credit: Araya Doheny/Getty Images for Baby2Baby

Kirsten Dunst and Jesse Plemons

Dunst stunned in her floral Dries Van Noten gown.

Credit: Araya Doheny/Getty Images for Baby2Baby

Ari Fournier and Cole Sprouse

Fournier donned an archive black Elie Saab gown with a thigh-high slit while Sprouse wore a sleekly tailored black suit.